Product ID:1,1,1-TRICHLOROETHANE;SOLVENT 111;SS-102;METHYL CHLOROFORM
MSDS Date:01/01/1990
FSC:6810
NIIN:00-476-5613
MSDS Number: BXVPP

V.O. BAKER

MENTOR, OH 44061-0055
US

Emergency Phone: 316-524-5751/415-821-5338

Info Phone: 216-255-1020/800-321-3572

Cage: 8T692

V O BAKER DIST CO

55 MENTOR, OH 44061-0055 US

Telephone: 216-255-1020

Cage: 8T692

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA 313)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 96.5%

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM/450STEL;9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,4-DIOXANE (DIETHYLENE DIOXIDE) (SARA 313) (CERCLA)

CAS: 123-91-1

RTECS: JG8225000

Fraction By Weight: <3.0%

OSHA PEL S, 100 PPM

ACGIH TLV: S, 25 PPM; 9495

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

1,2-BUTYLENE OXIDE (SARA 313) (CERCLA)

CAS: 106-88-7

RTECS: EK3675000

Fraction By Weight: >0.5%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:MIN EFFECTS OBSERVED
<1000PPM;DIZZ,DROWS,THROAT IRRIT >1000PPM.UNCONSC/DEATH POSSIBLE
>10000PPM.BLOOD PRESSURE DEPRESSION,CARDIAC
SENSITIZATION,VENTRICULAR ARRHYTHMIA CAN RESULT FRM EXPO TO NEAR
-ANESTHETIC LEVELS.AEROSOL FORM MORE ACUTELY TOXIC THAN
VAP.SKIN:PROL/REP CONTACT IRRIT,DEFATT,DERM.ABSOPTION (SUPPLEM)
Explanation of Carcinogenicity:PER MSDS:PRODUCT NOT LISTED ON
OSHA/IARC/NTP CARCINOGEN LISTS.NOT CARCINOGENIC TO LAB
ANIMALS.REPRODUCTIVE ANIMAL TOXICI
Effects of Overexposure:DIZZINESS, DROWSINESS,THROAT IRRIT.
UNCONSC,DEATH,BLOOD PRESSURE DEPRESSION, CARDIAC SENSITIZATION,
VENTRICULAR ARRHYTHMIA, SKIN IRRIT, DEFATTING, DERM. SLIGHT TEMP
EYE IRRIT W/SLIGHT TEMP CORNEAL INJ URY.ASPIRATION INTO LUNGS
CAUSES CHEM PNEUMONIA & SYSTEMIC EFFECTS.
Medical Cond Aggravated by Exposure:ACUTE & CHRONIC LIVER DISEASE &
RHYTHM DISORDERS OF THE HEART.

First Aid:INHAL:REMOVE TO FRESH AIR.STOP BREATH ADMINISTER ART
RESP.CALL DR. SKIN:REMOVE CONTAMIN CLOTH/SHOES.WASH W/SOAP/WATER.
EYES:FLUSH IMMED W/WATER FOR @LEAST 15MINS.IRRIT PERSISTS CALL DR.
INGEST:DO NOT INDUCE VOMIT.CONTACT DR/EMERG MED FACILITY IMMED.
NOTE TO DR:ADRENALIN SHOULD NEVER BE GIVEN TO PERSONS OVEREXPOSED
TO 1,1,1-TRICHLOROETHANE.

Flash Point Method:TCC
Flash Point:NONE
Lower Limits:7.5
Upper Limits:15
Extinguishing Media:WATER, FOAM, DRY CHEMICAL, CARBON DIOXIDE (CO2).
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR SELF-CONTAINED
POSITIVE-PRESSURE BREATHING APPARATUS DUE TO THERMAL DECOMPOSITION
PRODUCTS AND AVOID SKIN CONTACT.
Unusual Fire/Explosion Hazard:CONCENTRATED VAPORS CAN BE IGNITED BY
HIGH INTENSITY IGNITION SOURCE.

Spill Release Procedures:EVACUATE AREA.VENTILATE.AVOID BREATH VAPS.DIKE
TO CONTAIN SPILL.CLEANUP(WEAR PROT EQPMT)BY M OPPING OR W/ABSORBENT
MATL.PLACE IN CLSD CNTNR FOR DISPOSAL.AVOID CONTAMIN OF GROUND &
SURFACE WATERS.DO TO FLUSH TO SEWER.IF INDOORS TURN OFF
AIRCOND/HEAT

Handling and Storage Precautions:AVOID CONTACT W/SKIN/BREATH VAP.DO NOT
EAT/DRINK/SMOKE WORKAREA.STORE LABEL/SEAL CNTNRS IN
COOL,DRY,WELL-VENTI AREA.PREVENT WATER/MOIST AIR ENTER CNTR
Other Precautions:DETERMINE EXPO LEVEL BY MONITORING PERFORMED
REGRLY.NOTE:SELECT/USE/MAINTIAN PROT EQMPT/CLOTH IAW APPLICABLE
STDS/REGS.ADDN INFO CONTACT CLOTH/EQPMT MFG OR VULCAN CHEM TECHN
SERV DEPT.VAP HEAVIER THAN AIR;COLLECT IN LOW AREAS;SEE ASTMD4276.

Respiratory Protection:WHERE VAP CONCEN EXCEEDS/LIKELY TO EXCEED 350PPM
NIOSH/MSHA APPROVED ORG VAP TYP RESP ACCEPTABLE.NIOSH/MSHA APPROVED
SCBA OR AIRLINE RESP W/FULL FACEPC REQUIRED FOR VAP CONCEN >1000PPM
& FOR SPILLS &/ OR EMERG.FOLLOW APPLICABLE RESP STD/REGS
Ventilation:DO NOT USE IN CLOSED OR CONFINED SPACE. OPEN DOORS &/OR
WINDOWS. USE VENTILATION TO MAINTAIN EXPO LEVELS BELOW 350PPM.
Protective Gloves:VITON,POLYVINYL ALCOHOL,EQUIVALENT GLOVE
Eye Protection:SAF GLASS,CHEM GOGG &/OR FACESHIELDS.
Other Protective Equipment:SOLVENT-RESIST BOOTS/APRON/HEAGEAR &/OR
FACESHIELD.CONTACT LENESE SHOULDN'T BE WORN.SAFETY SHOWER,EYEWASH
STATIONS.
Work Hygienic Practices:WASH CONTAMIN CLOTH/SHOES BEFORE REUSE. WASH
HANDS WELL AFTER HANDLING & PRIOR TO EAT/DRINK/USE RESTROOM.
Supplemental Safety and Health
HEALTH HAZ:POSSIBLE W/PROLONG CONTACT.PURE Q,4-DIETHYLENE DIOXIDE
READILY ABSORBE THRU INTACT SKIN.EYES:SLIGHT TEMP IRRIT W/SLIGHT
TEMP CORNEAL INJURY.VAP IRRIT.INGEST:SINGLE DOSE TOXICITY IS
LOW-MODE RATE.ASPIRATED INTO LUNGS FRM VOMIT CAUSING CHEM PNEUMONIA
& SYS EFFECTS.

HCC:T4
Boiling Pt:B.P. Text:165F,74C
Vapor Pres:100 @20C
Vapor Density:4.6
Spec Gravity:1.32
pH:7/K
Evaporation Rate & Reference:0.4, ETHER-1
Solubility in Water:0.07G/100G @25C
Appearance and Odor:CLEAR, COLOLESS LIQUID, MILDLY SWEET ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES,OXIDIZERS,REACTIVE METALS(IE
ALUMINUM,POTASSIUM,SODIUM,ETC).
Stability Condition to Avoid:AVOID CONTACT W/OPEN FLAME, ELECTRIC ARCS,
OR OTHER HOT SURFACES WHICH CAN CAUSE THERMAL DECOMPOSITION.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, CHLORINE.

Waste Disposal Methods:DO NOT REUSE DR W/O RECYCLING/RECONDITIONING IAW
APPLICABLE FED/STATE/LOC LAWS.RECOVERED LIQ MAY BE SENT TO LICENSED
RECLAIMER/INCINERATION FACILITY.CONTAMIN MATL MUST BE DISPOSED OF
IN PERMITTED WAST E MGT FACILITY.CONSULT FED/STATE/LOC AUTHORITIES.

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document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.